Solubility and pH calculations : the mathematics of the simplest ionic equilibria / James Newton Butler. Ionic Equilibrium: Solubility and pH Calculations James N. Butler Hardcover 978-0-471-58526-8 April 1998 Print-on-demand $212.25 DESCRIPTION A celebrated classic in the field updated and expanded to includethe latest computerized calculation techniques In addition, the solubility of simple binary compounds such as oxides and sulfides, both strong bases, is often dependent on pH. Then read and study the Ionic Equilibrium book, this will give you a view of the trees. All rights reserved. Ionic Equilibrium: Solubility and pH Calculations By J. N. Butler (Harvard University); with a chapter by David R. Cogley. Chem. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. For example, the anion in many sparingly soluble salts is the conjugate base of a weak acid that may become protonated in solution. I suggest that you first read and study the Solubility and pH Calculations book. 1. Share. Would you like to change to the site? In addition, the solubility of simple binary compounds such as oxides and sulfides, both strong bases, is often dependent on pH. Get article recommendations from ACS based on references in your Mendeley library. Download Product Flyer is to download PDF in new tab. Peter Englezos Surprising experiences. This is a dummy description. Download Product Flyer is to download PDF in new tab. A celebrated classic in the field updated and expanded to includethe latest computerized calculation techniques In 1964, James N. Butler published a book in which he presentedsome simple graphical methods of performing acid-base, solubility,and complex formation equilibrium calculations. The solubility of many compounds depends strongly on the pH of the solution. Solubility and pH Calculations (Butler, James N.) ACS; ACS Publications; C&EN; CAS; Find my institution. [Book] Ionic Equilibrium: Solubility and pH Calculations by by James N. Butler A celebrated classic in the field updated and expanded to include the latest computerized calculation techniques In 1964, James N. Butler published a book in which he presented some simple graphical methods This next example shows you how to cope if the ratio is different. For example, the anion in many sparingly soluble salts is the conjugate base of a weak acid that may become protonated in solution. I used the Ionic Equilibrium book for a class I taught to Chemical Engineers at Rowan University a couple years ago. is the capacity of a solute to dissolve in a pure solvent. Copyright © 2000-document.write(new Date().getFullYear()) by John Wiley & Sons, Inc., or related companies. 1876] dictates that under a fixecl temperature and pressurc. Find more information on the Altmetric Attention Score and how the score is calculated. Table 1 lists the Ksp values of the various calcium phosphate com-pounds that herve been determined by clifferent ir.rvcstigators. General Chemistry Reference Text. Download Product Flyer is to download PDF in new tab. "This is by far the best textbook on chemical equilibrium I know. All Publications/Website. These calculations are very simple if you have a compound in which the numbers of positive and negative ions are 1 : 1. 576 Pages, Request permission to reuse content from this site. Example 1. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. ISBN 0-471-58526-2. The solubility of many compounds depends strongly on the pH of the solution. Log In. the Altmetric Attention Score and how the score is calculated. You are currently using the site but have requested a page in the site. Ionic Equilibrium:  Solubility and pH Calculations By J. N. Butler (Harvard University); with a chapter by David R. Cogley. the equilibrium solubility of an ionizable compound at a pH where ionized form is also present ... complicated equations for calculation the experiments must be checked. Find more information about Crossref citation counts. If we add H+ ions (decrease the pH), Mg(OH) 2 will become more soluble. a three-component system, such as Ca(OH)2-H3PO4-H2O. ISBN 0-471-58526-2. We can derive a simple equation for buffer calculations: ... pH The solubility of a substance can depend on pH. Facebook; Twitter; WeChat; Linked In; Reddit; Email; J. Chem. Acid-base equilibria and calculations Your Mendeley pairing has expired. Calculate the solubility … April 1998 Citations are the number of other articles citing this article, calculated by Crossref and updated daily. It is an absolute must for everybody using electrolyte solutions in his research..."(Jnl of Solid State Electrochemistry, Vol 5, 2001), COVID-19 Discipline-Specific Online Teaching Resources, Peer Review & Editorial Office Management, The Editor's Role: Development & Innovation, People In Research: Interviews & Inspiration. 3. • definition of pH and the pH scale • strong vs. weak acids and bases • the names of the common acids and bases. 1998. xi + 559 pp. Solubility Phase Diagrams Cibbs'phase rule [Gibbs. Wiley & Sons, Inc.:  New York. Solubility. You have to login with your ACS ID befor you can login with your Mendeley account. A celebrated classic in the field updated and expanded to includethe latest computerized calculation techniques. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Synthesis and Structure−Activity Relationships of 2-Pyrazinylcarboxamido- benzoates and … the solubility as a function of pH and other solution parameters as described next. This is a dummy description. These metrics are regularly updated to reflect usage leading up to the last few days. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. You’ve supercharged your research process with ACS and Mendeley! ISBN: 978-0-471-58526-8 Educ. This will give you a view of the forest. Find more information about Crossref citation counts. The solubility of magnesium hydroxide at 298 K is 1.71 x 10-4 mol dm-3. Recently Viewed. Such pH-dependent solubility is not restricted to salts that contain anions derived from water. ... • If the solute is ionizable and/or a weak electrolyte, altering the solvent pH can affect the surface/saturation concentration, C. s. This article has not yet been cited by other publications. Wiley & Sons, Inc.: New York. This is a dummy description. For example, consider Mg(OH) 2(s) Mg 2+(aq) + 2OH–(aq) At equilibrium, if we add OH– ions (increase the pH) the equilibrium will shift to the left, decreasing the solubility of Mg(OH) 2. Please reconnect. 1998. xi + 559 pp. Journal of Medicinal Chemistry. This is a dummy description. OR SEARCH CITATIONS My Activity. JAMES N. BUTLER, PhD, is Gordon McKay Professor of Applied Chemistry in the Division of Engineering and Applied Sciences at Harvard University. Solubility and dissolution are different concepts, but are related. Download Product Flyer is to download PDF in new tab.